First-principles study of phonon linewidths in noble metals

Phonon lifetimes in Cu, Ag, and Au at low and high temperatures were calculated along high symmetry directions using density functional theory combined with second-order perturbation theory. Both harmonic and third-order anharmonic force constants were computed using a supercell small displacement method, and the two-phonon densities of states were calculated for all three-phonon processes consistent with the kinematics of energy and momentum conservation. A nonrigorous Grüneisen model with no q-dependence of the anharmonic coupling constants offers a simple separation of the potential and the kinematics, and proved semiquantitative for Cu, Ag, and Au. A rule is reported for finding the most anharmonic phonon mode in fcc metals

Phonon anharmonicity of rutile TiO_2 studied by Raman spectrometry and molecular dynamics simulations

Raman spectra of rutile titanium dioxide (TiO_2) were measured at temperatures from 100 to 1150 K. Each Raman mode showed unique changes with temperature. Beyond the volume-dependent quasiharmonicity, the explicit anharmonicity was large. A new method was developed to fit the thermal broadenings and shifts of Raman peaks with a full calculation of the kinematics of three-phonon and four-phonon processes, allowing the cubic and quartic components of the anharmonicity to be identified for each Raman mode. A dominant role of phonon-phonon kinematics on phonon shifts and broadenings is reported. Force-field molecular dynamics calculations with the Fourier-transformed velocity autocorrelation method were also used to perform a quantitative study of anharmonic effects, successfully accounting for the anomalous phonon anharmonicity of the B_1_(g) mode

Anharmonicity-induced phonon broadening in aluminum at high temperatures

Thermal phonon broadening in aluminum was studied by theoretical and experimental methods. Using second-order perturbation theory, phonon linewidths from the third-order anharmonicity were calculated from first-principles density-functional theory (DFT) with the supercell finite-displacement method. The importance of all three-phonon processes were assessed and individual phonon broadenings are presented. The good agreement between calculations and prior measurements of phonon linewidths at 300 K and new measurements of the phonon density of states to 750 K indicates that the third-order phonon-phonon interactions calculated from DFT can account for the lifetime broadenings of phonons in aluminum to at least 80% of its melting temperature

Compensation for Maritime Ecological Damages in China Judicial Practice

The Article discusses the judicial experience of compensation for maritime ecological damages in China. The discussion focusse on the verdict of “Tasman sea” oil spill case. Scope and methods of assessment of ecological damages are major part of the discussion. Because of the absence of legislation on compensation for maritime ecological damages, the verdict is a significant guide to similar case trial in the future

STILN: A Novel Spatial-Temporal Information Learning Network for EEG-based Emotion Recognition

The spatial correlations and the temporal contexts are indispensable in Electroencephalogram (EEG)-based emotion recognition. However, the learning of complex spatial correlations among several channels is a challenging problem. Besides, the temporal contexts learning is beneficial to emphasize the critical EEG frames because the subjects only reach the prospective emotion during part of stimuli. Hence, we propose a novel Spatial-Temporal Information Learning Network (STILN) to extract the discriminative features by capturing the spatial correlations and temporal contexts. Specifically, the generated 2D power topographic maps capture the dependencies among electrodes, and they are fed to the CNN-based spatial feature extraction network. Furthermore, Convolutional Block Attention Module (CBAM) recalibrates the weights of power topographic maps to emphasize the crucial brain regions and frequency bands. Meanwhile, Batch Normalizations (BNs) and Instance Normalizations (INs) are appropriately combined to relieve the individual differences. In the temporal contexts learning, we adopt the Bidirectional Long Short-Term Memory Network (Bi-LSTM) network to capture the dependencies among the EEG frames. To validate the effectiveness of the proposed method, subject-independent experiments are conducted on the public DEAP dataset. The proposed method has achieved the outstanding performance, and the accuracies of arousal and valence classification have reached 0.6831 and 0.6752 respectively

Structural Relationship between Negative Thermal Expansion and Quartic Anharmonicity of Cubic ScF_3

Cubic scandium trifluoride (ScF_3) has a large negative thermal expansion over a wide range of temperatures. Inelastic neutron scattering experiments were performed to study the temperature dependence of the lattice dynamics of ScF3 from 7 to 750 K. The measured phonon densities of states show a large anharmonic contribution with a thermal stiffening of modes around 25 meV. Phonon calculations with first-principles methods identified the individual modes in the densities of states, and frozen phonon calculations showed that some of the modes with motions of F atoms transverse to their bond direction behave as quantum quartic oscillators. The quartic potential originates from harmonic interatomic forces in the DO_9 structure of ScF_3, and accounts for phonon stiffening with the temperature and a significant part of the negative thermal expansion

THE INFLUENCE MECHANISMS OF ILLEGITIMATE TASKS ON EMPLOYEES’ SILENCE BEHAVIORS AGAINST THE BACKDROP OF ARTIFICIAL INTELLIGENCE AND FUZZY ALGORITHMS

Employee silence can degrade the working environment and decrease employees’ motivation and commitment to an organization. As a result, it not only affects employees but also reduces the productivity of the organization. However, few studies have investigated the influencing mechanisms of employee silence empirically. This paper studies how illegitimate tasks affect employee silence based on artificial intelligence and fuzzy algorithms. We surveyed 325 employees in several medium-sized enterprises in Jiangsu and Anhui, China. According to the findings, emotional exhaustion partially mediates the relationship between illegitimate tasks and employees’ silence behaviors, and leadership humor can moderate the positive effect of illegitimate tasks on emotional exhaustion. Therefore, situating the mechanisms underlying employees’ silence behaviors in the context of artificial intelligence and fuzzy algorithm research helps researchers understand the relationship between illegitimate tasks and employees’ silence behaviors, thus improving related research on silence behaviors